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K‑Doped Co−Mn−Al Mixed Oxide Catalyst for N2O Abatement from\nNitric Acid Plant Waste Gases: Pilot Plant Studies.
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SYSNO ASEP 0467592 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title K‑Doped Co−Mn−Al Mixed Oxide Catalyst for N2O Abatement from
Nitric Acid Plant Waste Gases: Pilot Plant Studies.Author(s) Pacultová, K. (CZ)
Karásková, K. (CZ)
Kovanda, F. (CZ)
Jirátová, Květa (UCHP-M) RID, ORCID, SAI
Šrámek, J. (CZ)
Kustrovski, P. (PL)
Kotarba, A. (PL)
Chromčáková, Ž. (CZ)
Kočí, K. (CZ)
Obalová, L. (CZ)Source Title Industrial and Engineering Chemistry Research. - : American Chemical Society - ISSN 0888-5885
Roč. 55, č. 26 (2016), s. 7076-7084Number of pages 9 s. Language eng - English Country US - United States Keywords Co-Mn-Al mixed oxide ; N2O decomposition ; HNO3 pilot plant Subject RIV CI - Industrial Chemistry, Chemical Engineering R&D Projects GA14-13750S GA ČR - Czech Science Foundation (CSF) TA01020336 GA TA ČR - Technology Agency of the Czech Republic (TA ČR) Institutional support UCHP-M - RVO:67985858 UT WOS 000379455400003 EID SCOPUS 84978043368 DOI 10.1021/acs.iecr.6b01206 Annotation The K-doped Co−Mn−Al mixed oxide deN2O catalyst was prepared by calcination of Co−Mn−Al layered double hydroxide, subsequent impregnation with KNO3, and shaping into tablets of 5 mm × 5 mm. Tablets were tested for N2O decomposition in pilot scale reactor connected at the bypassed tail gas from the nitric production plant downstream of the SCR NOx/NH3 catalyst with the aim to perform kinetic measurements. The obtained kinetic data were applied in modeling of a fullscale reactor for the N2O emissions abatement and can be used for estimation of the amount of the catalyst necessary for obtaining required N2O conversion in the target plant. Workplace Institute of Chemical Process Fundamentals Contact Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Year of Publishing 2017
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