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Bulk Inclusions of Pyridazine-Based Molecular Rotors in Tris(o-phenylenedioxy)cyclotriphosphazene (TPP)

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    SYSNO ASEP0466267
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleBulk Inclusions of Pyridazine-Based Molecular Rotors in Tris(o-phenylenedioxy)cyclotriphosphazene (TPP)
    Author(s) Dron, P. I. (US)
    Zhao, K. (US)
    Kaleta, Jiří (UOCHB-X) RID, ORCID
    Shen, Y. (US)
    Wen, J. (US)
    Shoemaker, R. K. (US)
    Rogers, C. T. (US)
    Michl, Josef (UOCHB-X) RID, ORCID
    Source TitleAdvanced Functional Materials - ISSN 1616-301X
    Roč. 26, č. 31 (2016), s. 5718-5732
    Number of pages15 s.
    Languageeng - English
    CountryDE - Germany
    Keywordsdielectric spectroscopy ; inclusion compounds ; molecular rotors ; pyridazine ; solid-state NMR
    Subject RIVCC - Organic Chemistry
    Institutional supportUOCHB-X - RVO:61388963
    UT WOS000383568300013
    EID SCOPUS84971613803
    DOI10.1002/adfm.201600437
    AnnotationA new class of rod-shaped strongly dipolar molecular rotors for insertion into channels of hexagonal tris(o-phenylenedioxy)cyclotriphosphazene (TPP) has been examined. Seven different 3,6-disubstituted pyridazines and one singly 3-substituted system have been prepared and studied by solid-state nuclear magnetic resonance (NMR), X-ray powder diffraction, and dielectric spectroscopy. NMR and X-ray diffraction both show that all but one of these molecular rotors form hexagonal bulk inclusion compounds with TPP. In-plane lattice parameters for the hexagonal phases increase with the size of the end group, which also controls the energy barriers for rotation of the pyridazine dipole. The barriers range from approximate to 4 kcal mol(-1) for small or flexible end groups to less than 0.7 kcal mol(-1) for 3-methylbicyclo[1.1.1]pent-1-yl end groups after annealing to 235 degrees C, and an interpretation of these differences is offered. Computer modeling of the relaxed TPP channels followed by density functional calculation of the environment for one of the rotors provides quantitative agreement with the observed barrier. The systems with the lowest rotational barriers show signs of collective behavior, discussed in terms of antiferroelectric intrachannel and ferroelectric interchannel dipole-dipole interactions. A Curie temperature of 22 K is deduced for 3,6-diadamant-1-ylpyridazine, but no ordered dielectric phases are found. Conclusions have been drawn for improved rotor design.
    WorkplaceInstitute of Organic Chemistry and Biochemistry
    Contactasep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Viktorie Chládková, Tel.: 232 002 434
    Year of Publishing2017
Number of the records: 1  

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