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Control of reactivity and regioselectivity for on-surface dehydrogenative aryl-aryl bond formation
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SYSNO ASEP 0461488 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Control of reactivity and regioselectivity for on-surface dehydrogenative aryl-aryl bond formation Author(s) Kocić, N. (DE)
Liu, X. (CH)
Chen, S. (CH)
Decurtins, S. (CH)
Krejčí, Ondřej (FZU-D)
Jelínek, Pavel (FZU-D) RID, ORCID
Repp, J. (DE)
Liu, S. (CH)Source Title Journal of the American Chemical Society. - : American Chemical Society - ISSN 0002-7863
Roč. 138, č. 17 (2016), s. 5585-5593Number of pages 9 s. Language eng - English Country US - United States Keywords on-surface reaction ; AFM ; DFT ; metal-organic coordination Subject RIV CF - Physical ; Theoretical Chemistry R&D Projects GC14-16963J GA ČR - Czech Science Foundation (CSF) Institutional support FZU-D - RVO:68378271 UT WOS 000375521100024 EID SCOPUS 84969211415 DOI 10.1021/jacs.5b13461 Annotation Here we exploit a combined STM/AFM technique to demonstrate the on-surface formation of complex molecular architectures built up from a heteroaromatic precursor, the tetracyclic pyrazino[2,3-f][4,7]phenanthroline (pap) molecule. Selective intermolecular aryl–aryl coupling via dehydrogenative C–H activation occurs on Au(111) upon thermal annealing under ultrahigh vacuum (UHV) conditions. Workplace Institute of Physics Contact Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579 Year of Publishing 2017
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