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Cross-linking multiwall carbon nanotubes using PFPA to build robust, flexible and highly aligned large-scale sheets and yarns

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    SYSNO ASEP0458596
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleCross-linking multiwall carbon nanotubes using PFPA to build robust, flexible and highly aligned large-scale sheets and yarns
    Author(s) Inoue, Y. (JP)
    Nakamura, K. (JP)
    Miyasaka, Y. (JP)
    Nakano, T. (JP)
    Kletetschka, Günther (GLU-S) RID, SAI, ORCID
    Source TitleNanotechnology. - : Institute of Physics Publishing - ISSN 0957-4484
    Roč. 27, č. 11 (2016)
    Number of pages11 s.
    Publication formPrint - P
    Languageeng - English
    CountryGB - United Kingdom
    Keywordsmulti-walled carbon nanotube ; nano-mechanical properties ; cross-linking ; PFPA ; dry spinning ; yarn
    Subject RIVBN - Astronomy, Celestial Mechanics, Astrophysics
    Institutional supportGLU-S - RVO:67985831
    UT WOS000370259800025
    EID SCOPUS84959223681
    DOI10.1088/0957-4484/27/11/115701
    AnnotationMulti-walled carbon nanotube (CNT) structures, including unidirectionally aligned sheets and spun yarns, were fabricated by direct dry-spinning methods from spinnable CNT arrays. We improved the mechanical properties of the CNT structures. CNTs were tailored in sheets and yarns using perfluorophenyl azide (PFPA) as a binding agent. The azide group of PFPA bonds to graphene crystal surfaces under UV radiation exposed for 1 h. For the CNT sheet, Young's modulus increased from 1.6 to 32.9 GPa and tensile strength increased from 35.9 MPa to 144.5 MPa. For the CNT yarns Young's modulus increased from 29.5 to 78.0 GPa and tensile strength increased from 639.1 to 675.6 MPa. With this treatment, the CNT sheets became more robust and more flexible materials. Since cross-linking of CNTs by PFPA is a simple and rapid process, it is suitable for fabrication of enhanced CNT materials.
    WorkplaceInstitute of Geology
    ContactJana Popelková, popelkova@gli.cas.cz, Sabina Janíčková, Tel.: 233 087 272
    Year of Publishing2017
Number of the records: 1  

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