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10-Vertex closo-carborane: a unique ligand platform for porous coordination polymers

SYSNO ASEP	0458229
Document Type	J - Journal Article
R&D Document Type	Journal Article
Subsidiary J	Článek ve WOS
Title	10-Vertex closo-carborane: a unique ligand platform for porous coordination polymers
Author(s)	Boldog, Ishtvan (UACH-T)_{SAI, RID, ORCID} Bereciartua, P.J. (ES) Bulánek, R. (CZ) Kučeráková, Monika (FZU-D)_{RID, ORCID} Tomandlová, Markéta (UACH-T)_SAI Dušek, Michal (FZU-D)_{RID, ORCID, SAI} Macháček, Jan (UACH-T)_{RID, ORCID, SAI} De Vos, D. (BE) Baše, Tomáš (UACH-T)_{RID, SAI, ORCID}
Number of authors	9
Source Title	CrystEngComm. - : Royal Society of Chemistry - ISSN 1466-8033 Roč. 18, č. 12 (2016), s. 2036-2040
Number of pages	5 s.
Language	eng - English
Country	GB - United Kingdom
Keywords	Metal-organic frameworks ; Surface-areas ; Pore-size ; Methane
Subject RIV	CA - Inorganic Chemistry
Subject RIV - cooperation	Institute of Physics - Solid Matter Physics ; Magnetism
R&D Projects	GA15-12653S GA ČR - Czech Science Foundation (CSF)
	GA14-03276S GA ČR - Czech Science Foundation (CSF)
	LO1603 GA MŠMT - Ministry of Education, Youth and Sports (MEYS)
Institutional support	UACH-T - RVO:61388980 ; FZU-D - RVO:68378271
UT WOS	000372282100001
EID SCOPUS	84961768114
DOI	10.1039/C5CE02501J
Annotation	1,10-Dicarboxy-1,10-dicarba-closo-decaborane, a classical dicarboxylate spacer ligand type similar to the prototypical terephthalic acid, proved to be different not only from the latter, but also from its closest relative compound, 1,12-dicarboxy-closo-1,12-dicarbadecaborane, with regard to the topology of its derived PCPs. Highly porous and robust compounds of zinc (rob net) and cobalt (‘quasi’ pcu) as well as a topologically unexpected copper compound (lvt) define the individuality of the 10-vertex carborane cage as a new fundamental spacer type in PCP chemistry. A combination of a lower steric demand compared to the 12-vertex analogue, a preferred orientation angle of 45° between the carboxylate planes and a moderately low rotation barrier are held responsible for the uniqueness of the 10-vertex analogue.
Workplace	Institute of Inorganic Chemistry
Contact	Jana Kroneislová, krone@iic.cas.cz, Tel.: 311 236 931
Year of Publishing	2017

Number of the records: 1