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Solid-Liquid Equilibria in Systems [Cxmim][Tf2N] with Diethylamine
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SYSNO ASEP 0443909 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Solid-Liquid Equilibria in Systems [Cxmim][Tf2N] with Diethylamine Author(s) Rotrekl, Jan (UCHP-M) RID, ORCID, SAI
Vrbka, P. (CZ)
Sedláková, Zuzana (UCHP-M) RID, ORCID, SAI
Wagner, Zdeněk (UCHP-M) RID, SAI, ORCID
Jacquemin, J. (GB)
Bendová, Magdalena (UCHP-M) RID, ORCID, SAISource Title Pure and Applied Chemistry. - : Walter de Gruyter - ISSN 0033-4545
Roč. 87, č. 5 (2015), s. 453-460Number of pages 8 s. Action International Symposium on Solubility Phenomena 2014 Event date 20.07.2014-24.07.2014 VEvent location Karlsruhe Country DE - Germany Event type EUR Language eng - English Country DE - Germany Keywords ionic liquids ; solid-liquid equilibria ; COSMO-RS Subject RIV CF - Physical ; Theoretical Chemistry R&D Projects LD14094 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) LG13060 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) Institutional support UCHP-M - RVO:67985858 UT WOS 000354956300003 EID SCOPUS 84983314199 DOI 10.1515/pac-2014-1119 Annotation In the present work, the solid-liquid-liquid equilibrium in the binary system of diethylamine (1) and ionic liquid (2) 1-methyl-3- ethylimidazolium bis(trifluoromethylsulfonyl)imide and solid-liquid equilibrium in system 1-methyl-3-butylimidazolium bis(trifluoromethylsulfonyl)imide was studied. Phase equilibrium was determined experimentally by means of a polythermic method. These data were then used to determine the activity coefficients for both ionic liquids. For the pure diethylamine the enthalpy of fusion was determined by differential scanning calorimetry, because to the best of our knowledge, this data is not yet reported in the open literature, a contrario of pure ionic liquids tested during this work. Workplace Institute of Chemical Process Fundamentals Contact Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Year of Publishing 2016
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