Immobilization of Helicene onto Carbon Substrates through Electropolymerization of [7]Helicenyl-thiophene

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SYSNO ASEP	0434457
Document Type	J - Journal Article
R&D Document Type	Journal Article
Subsidiary J	Článek ve WOS
Title	Immobilization of Helicene onto Carbon Substrates through Electropolymerization of [7]Helicenyl-thiophene
Author(s)	Hrbáč, J. (CZ) Storch, Jan (UCHP-M)_{RID, ORCID, SAI} Halouzka, V. (CZ) Církva, Vladimír (UCHP-M)_{RID, ORCID, SAI} Matějka, P. (CZ) Vacek, J. (CZ)
Source Title	RSC Advances. - : Royal Society of Chemistry Roč. 4, č. 86 (2014), s. 46102-46105
Number of pages	4 s.
Language	eng - English
Country	GB - United Kingdom
Keywords	electrochemical characterization ; solar cells ; polymer electrode
Subject RIV	CF - Physical ; Theoretical Chemistry
R&D Projects	TA01010646 GA TA ČR - Technology Agency of the Czech Republic (TA ČR)
Institutional support	UCHP-M - RVO:67985858
UT WOS	000342761600064
DOI	10.1039/c4ra06283c
Annotation	In this work, monomeric 3-([7]helicen-9-yl)thiophene was synthesized and used for the preparation of a polymeric film by electrosynthesis. The polymer prepared was characterized using Fe(CN)(6)(3-/4-) and Ru(NH3)(6)(3+/2+) redox probes, scanning electron microscopy and vibrational spectroscopy. The electropolymerization approach presented here provides a new option for the immobilization of helicenes onto solid supports.
Workplace	Institute of Chemical Process Fundamentals
Contact	Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227
Year of Publishing	2015

Number of the records: 1