Number of the records: 1
A new copper(I) coordination polymer with N.sub.2./sub.-donor schiff base and Its use as precursor for CuO nanoparticle: Spectroscopic, thermal and structural studies
- 1.
SYSNO ASEP 0434249 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title A new copper(I) coordination polymer with N2-donor schiff base and Its use as precursor for CuO nanoparticle: Spectroscopic, thermal and structural studies Author(s) Khalaji, A.D. (IR)
Rohlíček, Jan (FZU-D) RID, ORCID
Machek, Pavel (FZU-D) RID, ORCID, SAI
Das, D. (IN)Source Title Journal of Cluster Science - ISSN 1040-7278
Roč. 25, č. 5 (2014), s. 1425-1434Number of pages 10 s. Language eng - English Country US - United States Keywords copper(I) complex ; schiff base ; spectroscopy ; thermal study ; nanoparticle ; SEM ; XRD Subject RIV BM - Solid Matter Physics ; Magnetism Institutional support FZU-D - RVO:68378271 UT WOS 000342115700020 EID SCOPUS 84901578019 DOI 10.1007/s10876-014-0719-z Annotation A new copper(I) coordination polymer, [Cu((3,4-MeO-ba)2bn)I]n (1), using a bridging Schiff base ligand, N,N0-bis(3,4-dimethoxybenzylidene)butane-1,4-diamine, (3,4-MeO-ba)2bn, containing a flexible spacer (=N–CH2–CH2–CH2–CH2–N=) has been synthesized and characterized by elemental analyses (CHN) and FTIR spectroscopy, thermal analysis and powder X-ray structure analysis. In 1, Cu(I) ions are bridged by Schiff base ligands and iodine atoms forming 1D-chain. The thermal stability of 1 was studied by thermal gravimetric and differential thermal analyses. 1 is used to prepare CuO nanoparticles via solid state thermal decomposition in air and nanoparticles thus formed are characterized by scanning electron microscopy, transmission electron microscopy and powder X-ray diffraction techniques. Workplace Institute of Physics Contact Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579 Year of Publishing 2015
Number of the records: 1