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Atomic layer-deposited Al.sub.2./sub.O.sub.3./sub. coatings on NiTi alloy
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SYSNO ASEP 0432497 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Atomic layer-deposited Al2O3 coatings on NiTi alloy Author(s) Kei, C.C. (TW)
Yu, Y.S. (TW)
Racek, Jan (FZU-D) RID, ORCID
Vokoun, David (FZU-D) RID, ORCID
Šittner, Petr (FZU-D) RID, ORCIDSource Title Journal of Materials Engineering and Performance. - : Springer - ISSN 1059-9495
Roč. 23, č. 7 (2014), s. 2641-2649Number of pages 9 s. Action International Conference on Shape Memory and Superelastic Technologies (SMST 2013) Event date 21.05.2013-24.05.2013 VEvent location Praha Country CZ - Czech Republic Event type WRD Language eng - English Country US - United States Keywords ALD ; Al2O3 coating ; corrosion ; NiTi Subject RIV BM - Solid Matter Physics ; Magnetism R&D Projects GA101/09/0702 GA ČR - Czech Science Foundation (CSF) 7E11058 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) Institutional support FZU-D - RVO:68378271 UT WOS 000339010700052 EID SCOPUS 84904795412 DOI 10.1007/s11665-014-0956-1 Annotation Atomic layer deposition is introduced as a method suitable for preparation of Al2O3 layers on the surface of NiTi medical devices such as stents because of the excellent thickness control and conformal protective coating on complex structures. The corrosion properties of NiTi plates with Al2O3 coatings of various thicknesses in an environment similar to that occurring in the human body were studied using open circuit potential, potentiostatic electrochemical impedance spectroscopy, and cyclic polarization tests. It shows that the layer thickness plays a key role in the inhibition of corrosion. The thinner layers are more diffuse and make it easier for anodic reaction of passive NiTi with protective TiO2 underneath of Al2O3, while the thicker layers have the barrier effect with local pores initiating pitting corrosion. The results of our electrochemical experiments consistently show that corrosion properties of thick Al2O3 coatings on NiTi plate are inferior compared to the thin layers. Workplace Institute of Physics Contact Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579 Year of Publishing 2015
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