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Cementation and blackening of Holocene sands by peat-derived humates: A case study from the Great Dune of Pilat, Landes des Gascogne, Southwestern France
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SYSNO ASEP 0425586 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Cementation and blackening of Holocene sands by peat-derived humates: A case study from the Great Dune of Pilat, Landes des Gascogne, Southwestern France Author(s) Suchý, V. (CZ)
Sýkorová, Ivana (USMH-B) RID, ORCID
Havelcová, Martina (USMH-B) RID, ORCID
Machovič, Vladimír (USMH-B)
Zeman, Antonín (UTAM-F) RID, SAI
Trejtnarová, Hana (USMH-B)Source Title International Journal of Coal Geology. - : Elsevier - ISSN 0166-5162
Roč. 114, JUL (2013), s. 19-32Number of pages 14 s. Publication form Print - P Language eng - English Country NL - Netherlands Keywords humate ; peat ; cementation ; aeolian sand Subject RIV DB - Geology ; Mineralogy R&D Projects GA205/09/1162 GA ČR - Czech Science Foundation (CSF) GA13-18482S GA ČR - Czech Science Foundation (CSF) Institutional support USMH-B - RVO:67985891 ; UTAM-F - RVO:68378297 UT WOS 000320497000002 EID SCOPUS 84877323170 DOI 10.1016/j.coal.2013.03.012 Annotation The base sand layers of the aeolian Great Dune of Pilat, which stretches along the coast of Arcachon Bay, have been locally impregnated with a dark brown to black amorphous organic substance of humate composition. The humate-cemented sand forms a well-indurated horizon 40-50 cm in thickness that developed immediately beneath the Holocene peaty layer (P1 "paleosoil"). The humate, identified by means of FT-IR and Raman micro-spectroscopy, acted both as a cementing agent and as a coloring agent; it formed thin coats and meniscus cements between individual sandstone grains which, in turn, caused the dark, asphaltic-like appearance of the sandstone. Field observations, combined with geochemical analyses, and the presence of identical geochemical compounds recognized in the peat and sandstone humate cement, suggest that the peat-containing low-coalified (R-r = 0.2%) fragments of higher, submerged and floating plants and marine algae deposited in a saline and reducing environment served as an obvious source rock for the humate. The humate derived from decaying organic remains that descended from the peat into the permeable sand, where it indurated irreversibly over a period shorter than 3500 years. Workplace Institute of Rock Structure and Mechanics Contact Iva Švihálková, svihalkova@irsm.cas.cz, Tel.: 266 009 216 Year of Publishing 2014
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