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Photoluminescence studies of Li-doped Si nanocrystals
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SYSNO ASEP 0396399 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Photoluminescence studies of Li-doped Si nanocrystals Author(s) Klimešová, Eva (FZU-D) RID, ORCID
Vacík, Jiří (UJF-V) RID, ORCID, SAI
Holý, V. (CZ)
Pelant, Ivan (FZU-D) RID, ORCID, SAISource Title Nanomaterials and Nanotechnology - ISSN 1847-9804
Roč. 3, č. 14 (2013), s. 1-7Number of pages 7 s. Language eng - English Country HR - Croatia Keywords Si nanocrystals ; photoluminescence ; doping ; Li-ion batteries Subject RIV BM - Solid Matter Physics ; Magnetism R&D Projects GBP108/12/G108 GA ČR - Czech Science Foundation (CSF) Institutional support FZU-D - RVO:68378271 ; UJF-V - RVO:61389005 UT WOS 000331238000001 EID SCOPUS 84899553180 DOI 10.5772/56925 Annotation We investigate the optical properties of Li-doped Si nanocrystals (both freestanding and matrix-embedded), which are potentially an important material for the new generation of lithium-ion batteries. Our samples contain 10 – 100 Li atoms per one Si nanocrystal and their lattice is slightly expanded. The photoluminescence (PL) spectra of the S-band of Li-doped Si nanocrystals are blue-shifted by ~30nm compared to the undoped Si nanocrystals and their PL lifetime is correspondingly shorter. The F-band emission is almost unaffected by Li doping. The observed changes in the PL performance are probably caused by Si lattice expansion induced by Li insertion. The reported spectral blue shift is favourable for certain photonic applications. Workplace Institute of Physics Contact Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579 Year of Publishing 2014
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