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Defect structure of nanosized zirconium oxide powders doped with Y.sub.2./sub.O.sub.3./sub., Sc.sub.2./sub.O.sub.3./sub., Cr.sub.2./sub.O.sub.3./sub..
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SYSNO ASEP 0394500 Document Type C - Proceedings Paper (int. conf.) R&D Document Type Conference Paper Title Defect structure of nanosized zirconium oxide powders doped with Y2O3, Sc2O3, Cr2O3. Author(s) Yurchenko, L.P. (UA)
Bykov, I. P. (UA)
Brik, A.B. (UA)
Vasylyev, O.D. (UA)
Vereshchak, V.G. (UA)
Suchaneck, G. (DE)
Jastrabík, Lubomír (FZU-D) RID, ORCID
Dejneka, Alexandr (FZU-D) RID, ORCIDSource Title Oxide materials for electronic engineering - fabrication, properties and applications. - Zurich : Trans tech publications Ltd., 2013 / Ubizskii S. ; Vasylechko L. ; Zhydachevskii Y. - ISSN 1012-0394 Pages s. 108-113 Number of pages 6 s. Publication form Print - P Action International Scientific Conference on Oxide Materials for Electronic Engineering - Fabrication, Properties and Applications (OMEE 2012) Event date 03.09.2012-07.09.2012 VEvent location Lviv Country UA - Ukraine Event type WRD Language eng - English Country CH - Switzerland Keywords nanosized powder ; defects ; dopant ; electron paramagnetic resonance Subject RIV JA - Electronics ; Optoelectronics, Electrical Engineering CEZ AV0Z10100522 - FZU-D (2005-2011) UT WOS 000319786500018 EID SCOPUS 84876564695 DOI 10.4028/www.scientific.net/SSP.200.108 Annotation The formation mechanisms of paramagnetic centers originating from Zr3+ and Cr5+ ions and the influence of the nanoparticle composition on thermal generation processes of these paramagnetic centers were studied in ZrO2 structure by electron paramagnetic resonance. A set of nanosized zirconium oxide powders ( nominally pure ZrO2, ZrO2 doped with correspondingly Y2O3 and Sc2O3, Cr2O3 and Y2O3, as well as Cr2O3 ) was investigated. Annealing effects on the EPR lines of Zr3+ and Cr5+ ions were found to be different. Annealing curves of EPR signals caused by Cr5+ ions have a maximum in temperature range 500–600 oC. Mechanisms of Zr3+ and Cr5+ ions formation were discussed. Workplace Institute of Physics Contact Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579 Year of Publishing 2014
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