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High resolution characterization of uranium in sediments by DGT and DET techniques ACA-S-12-2197
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SYSNO ASEP 0386122 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title High resolution characterization of uranium in sediments by DGT and DET techniques ACA-S-12-2197 Author(s) Gregušová, Michaela (UIACH-O) ORCID
Dočekal, Bohumil (UIACH-O) RID, ORCIDNumber of authors 2 Source Title Analytica Chimica Acta. - : Elsevier - ISSN 0003-2670
Roč. 763, FEB 6 (2013), s. 50-56Number of pages 7 s. Publication form Print - P Language eng - English Country NL - Netherlands Keywords Diffusive gradient in thin films technique ; Diffusive equilibrium technique ; Uranium ; Sediment Subject RIV CB - Analytical Chemistry, Separation R&D Projects GAP503/10/2002 GA ČR - Czech Science Foundation (CSF) Institutional support UIACH-O - RVO:68081715 UT WOS 000314624900007 EID SCOPUS 84872594514 DOI 10.1016/j.aca.2012.12.001 Annotation Diffusive equilibrium (DET) and diffusive gradient in thin film (DGT) techniques with an inductively coupled plasma mass spectrometry detection of elements were applied to characterize uranium, manganese, iron and 238U/235U isotopic ratio depth profiles in sediment pore water at high spatial resolution and to monitor uranium uptake/remobilization processes in uranium spiked sediment core samples under laboratory, well controlled conditions. Modified constrained sediment DGT probes, packed with Spheron- Oxin® resin gel, were employed for selective uranium measurements. Spatially resolved DET and DGT responses were indicative of local redistribution of uranium in naturally uranium poor and rich sediments. Workplace Institute of Analytical Chemistry Contact Iveta Drobníková, drobnikova@iach.cz, Tel.: 532 290 234 Year of Publishing 2013
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