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Synthesis, crystal structure and conformational studies of Schiff-base compound 2-{[4-(Phenyldiazenyl)phenyl] iminomethyl}-5-bromophenolc
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SYSNO ASEP 0379219 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Synthesis, crystal structure and conformational studies of Schiff-base compound 2-{[4-(Phenyldiazenyl)phenyl] iminomethyl}-5-bromophenolc Author(s) Khalaji, A.D. (IR)
Fejfarová, Karla (FZU-D)
Dušek, Michal (FZU-D) RID, ORCID, SAI
Chermahini, A.N. (IR)Source Title Journal of Chemical Crystallography. - : Springer - ISSN 1074-1542
Roč. 42, č. 2 (2012), s. 136-140Number of pages 5 s. Language eng - English Country US - United States Keywords Shiff bases ; crystal structure ; X-ray diffraction ; Jana2006 Subject RIV BM - Solid Matter Physics ; Magnetism CEZ AV0Z10100521 - FZU-D (2005-2011) UT WOS 000301795600006 DOI 10.1007/s10870-011-0214-4 Annotation Schiff-base compound 2-{[4-(Phenyldiazenyl)-phenyl]iminomethyl}-5-bromophenol (1), containing an azo group was synthesized from the reaction of p-aminoazobenzene with 5-bromosalicylaldehyde and characterized by elemental analyses, FT-IR spectroscopy and X-ray single-crystal diffraction analysis. Molecular orbital calculation has been carried out using density functional method (B3LYP) at 6-31G basis set. Compound 1 crystallizes in the orthorhombic system, space group Pca21, with a = 12.1781(2) A, b = 4.4894(10) A, c = 27.7841(5) A, and Z = 4. Compound 1 displays a trans configuration with respect to the C=N and N=N double bonds. Workplace Institute of Physics Contact Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579 Year of Publishing 2013
Number of the records: 1