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Ruthenium metathesis catalyst bearing chelating carboxylate ligand immobilized on mesoporous molecular sieve SBA-15
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SYSNO ASEP 0376049 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Ruthenium metathesis catalyst bearing chelating carboxylate ligand immobilized on mesoporous molecular sieve SBA-15 Author(s) Bek, David (UFCH-W)
Gawin, R. (PL)
Grela, K. (PL)
Balcar, Hynek (UFCH-W) RID, ORCIDSource Title Catalysis Communication. - : Elsevier - ISSN 1566-7367
Roč. 21, MAY 5 2012 (2012), s. 42-45Number of pages 4 s. Language eng - English Country NL - Netherlands Keywords olefin metathesis ; hybrid catalyst ; ruthenium complexes Subject RIV CF - Physical ; Theoretical Chemistry R&D Projects IAA400400805 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) KAN100400701 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) GD203/08/H032 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z40400503 - UFCH-W (2005-2011) UT WOS 000303031100010 DOI 10.1016/j.catcom.2012.01.020 Annotation Ruthenium complex 3b bearing chelating carboxylate ligand was immobilized on mesoporous molecular sieve SBA-15 via cleavage of carboxylate by fluorocarboxylic acid groups introduced on the support surface. The hybrid olefin metathesis catalyst Ru/L/SBA-15, prepared straightforward without use of silver salts, exhibited high activity and selectivity in model metathesis reactions and low ruthenium leaching. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2013
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