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Ruthenium metathesis catalyst bearing chelating carboxylate ligand immobilized on mesoporous molecular sieve SBA-15

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    SYSNO ASEP0376049
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleRuthenium metathesis catalyst bearing chelating carboxylate ligand immobilized on mesoporous molecular sieve SBA-15
    Author(s) Bek, David (UFCH-W)
    Gawin, R. (PL)
    Grela, K. (PL)
    Balcar, Hynek (UFCH-W) RID, ORCID
    Source TitleCatalysis Communication. - : Elsevier - ISSN 1566-7367
    Roč. 21, MAY 5 2012 (2012), s. 42-45
    Number of pages4 s.
    Languageeng - English
    CountryNL - Netherlands
    Keywordsolefin metathesis ; hybrid catalyst ; ruthenium complexes
    Subject RIVCF - Physical ; Theoretical Chemistry
    R&D ProjectsIAA400400805 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR)
    KAN100400701 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR)
    GD203/08/H032 GA ČR - Czech Science Foundation (CSF)
    CEZAV0Z40400503 - UFCH-W (2005-2011)
    UT WOS000303031100010
    DOI10.1016/j.catcom.2012.01.020
    AnnotationRuthenium complex 3b bearing chelating carboxylate ligand was immobilized on mesoporous molecular sieve SBA-15 via cleavage of carboxylate by fluorocarboxylic acid groups introduced on the support surface. The hybrid olefin metathesis catalyst Ru/L/SBA-15, prepared straightforward without use of silver salts, exhibited high activity and selectivity in model metathesis reactions and low ruthenium leaching.
    WorkplaceJ. Heyrovsky Institute of Physical Chemistry
    ContactMichaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196
    Year of Publishing2013
Number of the records: 1  

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