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Permethylated 12-Vertex p-Carborane Self-Assembled Monolayers

SYSNO ASEP	0369307
Document Type	J - Journal Article
R&D Document Type	Journal Article
Subsidiary J	Článek ve WOS
Title	Permethylated 12-Vertex p-Carborane Self-Assembled Monolayers
Author(s)	Scholz, F. (DE) Nothofer, H. G. (DE) Wessels, J. M. (DE) Nelles, G. (DE) Wrochem von, F. (DE) Roy, S. (US) Chen, X. (US) Michl, Josef (UOCHB-X)_{RID, ORCID}
Number of authors	8
Source Title	Journal of Physical Chemistry C. - : American Chemical Society - ISSN 1932-7447 Roč. 115, č. 46 (2011), s. 22998-23007
Number of pages	10 s.
Language	eng - English
Country	US - United States
Keywords	p-carbone ; monolayer ; scanning tunneling microscopy ; ultraviolet photoelectron spectroscopy ; X-ray photoelectron
Subject RIV	CC - Organic Chemistry
CEZ	AV0Z40550506 - UOCHB-X (2005-2011)
UT WOS	000297001000040
DOI	10.1021/jp207133a
Annotation	closo-Carborane cages and their adsorption onto metal surfaces is a subject of growing interest because of the distinct structural and electronic properties of boron carbide derivatives. Nevertheless, the extent to which the substitution of the cage alters structural and spectroscopic characteristics of closo-carborane monolayers has not been investigated so far. In this paper, core level shifts and valence electronic structure of two different p-carboranes, the parent and the (2,11)-decamethylated 12-vertex closo-1,12-dicarbadodecaborane, are compared using photoemission spectroscopy, whereas the lateral arrangement of the molecules on gold is investigated by scanning tunneling microscopy.
Workplace	Institute of Organic Chemistry and Biochemistry
Contact	asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Viktorie Chládková, Tel.: 232 002 434
Year of Publishing	2012

Number of the records: 1