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Effect of Preparation of Pd and Pd-Pt Catalysts from Acid Leached Silica-Alumina on Their Activity in HDS of Thiophene and Benzothiophene

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    SYSNO ASEP0369112
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleEffect of Preparation of Pd and Pd-Pt Catalysts from Acid Leached Silica-Alumina on Their Activity in HDS of Thiophene and Benzothiophene
    Author(s) Vít, Zdeněk (UCHP-M) RID, SAI
    Kmentová, Hana (UCHP-M)
    Kaluža, Luděk (UCHP-M) RID, ORCID, SAI
    Gulková, Daniela (UCHP-M) RID, ORCID, SAI
    Boaro, M. (IT)
    Source TitleApplied Catalysis B - Environmental. - : Elsevier - ISSN 0926-3373
    108-109, 1-2 (2011), s. 152-160
    Number of pages9 s.
    Languageeng - English
    CountryNL - Netherlands
    Keywordshydrodesulfurization ; silica-alumina ; Pd-Pt catalyst
    Subject RIVCF - Physical ; Theoretical Chemistry
    R&D ProjectsGA104/09/0751 GA ČR - Czech Science Foundation (CSF)
    GAP106/11/0902 GA ČR - Czech Science Foundation (CSF)
    CEZAV0Z40720504 - UCHP-M (2005-2011)
    UT WOS000296044300019
    DOI10.1016/j.apcatb.2011.08.022
    AnnotationSilica-alumina (MSA) was modified by acid leaching and used as support of Pd and Pd-Pt catalysts. The leaching decreased the Al2O3 content from 52 to 9 wt.% and increased Brønsted acidity and BET surface area. This improved activities of Pd catalysts in HDS of thiophene and benzothiophene. The bimetallic Pd-Pt catalyst prepared from Pd acetate and Pt(NH3)4(OH)2 showed significant promotional effect in HDS.
    WorkplaceInstitute of Chemical Process Fundamentals
    ContactEva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227
    Year of Publishing2012
Number of the records: 1  

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