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Effect of Preparation of Pd and Pd-Pt Catalysts from Acid Leached Silica-Alumina on Their Activity in HDS of Thiophene and Benzothiophene
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SYSNO ASEP 0369112 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Effect of Preparation of Pd and Pd-Pt Catalysts from Acid Leached Silica-Alumina on Their Activity in HDS of Thiophene and Benzothiophene Author(s) Vít, Zdeněk (UCHP-M) RID, SAI
Kmentová, Hana (UCHP-M)
Kaluža, Luděk (UCHP-M) RID, ORCID, SAI
Gulková, Daniela (UCHP-M) RID, ORCID, SAI
Boaro, M. (IT)Source Title Applied Catalysis B - Environmental. - : Elsevier - ISSN 0926-3373
108-109, 1-2 (2011), s. 152-160Number of pages 9 s. Language eng - English Country NL - Netherlands Keywords hydrodesulfurization ; silica-alumina ; Pd-Pt catalyst Subject RIV CF - Physical ; Theoretical Chemistry R&D Projects GA104/09/0751 GA ČR - Czech Science Foundation (CSF) GAP106/11/0902 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z40720504 - UCHP-M (2005-2011) UT WOS 000296044300019 DOI 10.1016/j.apcatb.2011.08.022 Annotation Silica-alumina (MSA) was modified by acid leaching and used as support of Pd and Pd-Pt catalysts. The leaching decreased the Al2O3 content from 52 to 9 wt.% and increased Brønsted acidity and BET surface area. This improved activities of Pd catalysts in HDS of thiophene and benzothiophene. The bimetallic Pd-Pt catalyst prepared from Pd acetate and Pt(NH3)4(OH)2 showed significant promotional effect in HDS. Workplace Institute of Chemical Process Fundamentals Contact Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Year of Publishing 2012
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