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The Flow of Butane and Isobutene Vapors Near Saturation Through Porous Vycor Glass Membranes

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    SYSNO ASEP0367224
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleThe Flow of Butane and Isobutene Vapors Near Saturation Through Porous Vycor Glass Membranes
    Author(s) Loimer, T. (FR)
    Uchytil, Petr (UCHP-M) RID, SAI
    Petričkovič, Roman (UCHP-M) RID, SAI
    Setničková, Kateřina (UCHP-M) RID, ORCID, SAI
    Source TitleJournal of Membrane Science. - : Elsevier - ISSN 0376-7388
    Roč. 383, 1-2 (2011), s. 104-115
    Number of pages12 s.
    Languageeng - English
    CountryNL - Netherlands
    Keywordstransport processes ; porous media ; inorganic membranes
    Subject RIVCI - Industrial Chemistry, Chemical Engineering
    R&D ProjectsGA104/09/1165 GA ČR - Czech Science Foundation (CSF)
    GCP106/10/J038 GA ČR - Czech Science Foundation (CSF)
    ME 889 GA MŠMT - Ministry of Education, Youth and Sports (MEYS)
    CEZAV0Z40720504 - UCHP-M (2005-2011)
    UT WOS000296483300012
    DOI10.1016/j.memsci.2011.08.035
    AnnotationThe pressures of the vapors upstream of the membrane lie between the saturation pressure and approximately half the saturation pressure. The process is described assuming an adiabatic flow of the fluid. As an important result, the adiabatic description yields a characteristic pore diameter. For upstream pressures close to the saturation pressure and pore diameters smaller than the characteristic value, complete condensation of the fluid and flow of the liquid phase through a part of the membrane is predicted. Under these circumstances, due to the action of capillary pressure, the mass flux is greatly increased with respect to the mass flux of a vapor that does not undergo phase changes. Isothermal descriptions do not yield a characteristic pore diameter. There is qualitative agreement between our description and experimental data with respect to the mass transport. Quantitatively, the agreement is poor to moderate.
    WorkplaceInstitute of Chemical Process Fundamentals
    ContactEva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227
    Year of Publishing2012
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