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The Flow of Butane and Isobutene Vapors Near Saturation Through Porous Vycor Glass Membranes
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SYSNO ASEP 0367224 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title The Flow of Butane and Isobutene Vapors Near Saturation Through Porous Vycor Glass Membranes Author(s) Loimer, T. (FR)
Uchytil, Petr (UCHP-M) RID, SAI
Petričkovič, Roman (UCHP-M) RID, SAI
Setničková, Kateřina (UCHP-M) RID, ORCID, SAISource Title Journal of Membrane Science. - : Elsevier - ISSN 0376-7388
Roč. 383, 1-2 (2011), s. 104-115Number of pages 12 s. Language eng - English Country NL - Netherlands Keywords transport processes ; porous media ; inorganic membranes Subject RIV CI - Industrial Chemistry, Chemical Engineering R&D Projects GA104/09/1165 GA ČR - Czech Science Foundation (CSF) GCP106/10/J038 GA ČR - Czech Science Foundation (CSF) ME 889 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) CEZ AV0Z40720504 - UCHP-M (2005-2011) UT WOS 000296483300012 DOI 10.1016/j.memsci.2011.08.035 Annotation The pressures of the vapors upstream of the membrane lie between the saturation pressure and approximately half the saturation pressure. The process is described assuming an adiabatic flow of the fluid. As an important result, the adiabatic description yields a characteristic pore diameter. For upstream pressures close to the saturation pressure and pore diameters smaller than the characteristic value, complete condensation of the fluid and flow of the liquid phase through a part of the membrane is predicted. Under these circumstances, due to the action of capillary pressure, the mass flux is greatly increased with respect to the mass flux of a vapor that does not undergo phase changes. Isothermal descriptions do not yield a characteristic pore diameter. There is qualitative agreement between our description and experimental data with respect to the mass transport. Quantitatively, the agreement is poor to moderate. Workplace Institute of Chemical Process Fundamentals Contact Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Year of Publishing 2012
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