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Direct observation of triple ions in aqueous solutions of nickel(II) sulfate: A Molecular link between gas phase and bulk behavior
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SYSNO ASEP 0363851 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Direct observation of triple ions in aqueous solutions of nickel(II) sulfate: A Molecular link between gas phase and bulk behavior Author(s) Schröder, Detlef (UOCHB-X)
Ducháčková, L. (CZ)
Tarábek, Ján (UOCHB-X) RID, ORCID
Karwowska, M. (PL)
Fijalkowski, K. J. (PL)
Ončák, Milan (UFCH-W) ORCID, RID
Slavíček, Petr (UFCH-W) RIDNumber of authors 7 Source Title Journal of the American Chemical Society. - : American Chemical Society - ISSN 0002-7863
Roč. 133, č. 8 (2011), s. 2444-2451Number of pages 8 s. Language eng - English Country US - United States Keywords electrospray ionization ; infrared spectroscopy ; mass spectrometry ; microhydration ; nickel sulfate Subject RIV CF - Physical ; Theoretical Chemistry R&D Projects GA203/08/1487 GA ČR - Czech Science Foundation (CSF) LC512 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) KAN400400651 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) CEZ AV0Z40550506 - UOCHB-X (2005-2011) AV0Z40400503 - UFCH-W (2005-2011) UT WOS 000288291300028 DOI 10.1021/ja105408a Annotation Electrospray ionization of aqueous nickel(II) sulfate provides direct experimental evidence for the formation of triple ions of the type [Ni2(SO4)(H2O)n]2+ and [Ni(SO4)2]2-, whose existence in aqueous solution has previously been proposed based on relaxation spectroscopy. Workplace Institute of Organic Chemistry and Biochemistry Contact asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Viktorie Chládková, Tel.: 232 002 434 Year of Publishing 2012
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