Number of the records: 1
Effect of the Carboxylate Shift on the Reactivity of Zinc Complexes in the Gas Phase
- 1.
SYSNO ASEP 0363624 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Effect of the Carboxylate Shift on the Reactivity of Zinc Complexes in the Gas Phase Author(s) Ducháčková, L. (CZ)
Schröder, Detlef (UOCHB-X)
Roithová, J. (CZ)Number of authors 3 Source Title Inorganic Chemistry. - : American Chemical Society - ISSN 0020-1669
Roč. 50, č. 7 (2011), s. 3153-3158Number of pages 6 s. Language eng - English Country US - United States Keywords acetate ; infrared multiphoton dissociation ; mass spectrometry ; zinc Subject RIV CA - Inorganic Chemistry R&D Projects GA203/08/1487 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z40550506 - UOCHB-X (2005-2011) UT WOS 000288730400058 DOI 10.1021/ic2002767 Annotation The effect of different modes of the carboxylato ligands on the reactivity of gaseous zinc-acetate complexes is investigated by infrared multiphoton dissociation spectroscopy. In [(Imi)nZn(CH3COO)]+ complexes (Imi = imidazole, n = 1-3) the coordination changes from bi- to monodentate upon coordination of the third imidazole ligand ("carboxylate shift"). Workplace Institute of Organic Chemistry and Biochemistry Contact asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Viktorie Chládková, Tel.: 232 002 434 Year of Publishing 2012
Number of the records: 1