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Mechanisms of chemical generation of volatile hydrides for trace element determination (IUPAC Technical Report)

SYSNO ASEP	0362869
Document Type	J - Journal Article
R&D Document Type	Journal Article
Subsidiary J	Článek ve WOS
Title	Mechanisms of chemical generation of volatile hydrides for trace element determination (IUPAC Technical Report)
Author(s)	D'Ulivo, A. (IT) Dědina, Jiří (UIACH-O)_{RID, ORCID} Mester, Z. (CA) Sturgeon, R. E. (CA) Wang, Q. (CN) Welz, B. (BR)
Number of authors	6
Source Title	Pure and Applied Chemistry. - : Walter de Gruyter - ISSN 0033-4545 Roč. 83, č. 6 (2011), s. 1283-1340
Number of pages	58 s.
Language	eng - English
Country	US - United States
Keywords	borane complexes ; chemical generation of volatile hydrides (CHG) ; volatile hydrides
Subject RIV	CB - Analytical Chemistry, Separation
CEZ	AV0Z40310501 - UIACH-O (2005-2011)
UT WOS	000290852100006
DOI	10.1351/PAC-REP-09-10-03
Annotation	This report is focused on the rationalization and clarification of fundamental aspects related to CHG: mechanism of hydrolysis of borane complexes; mechanism of hydrogen transfer from the borane complex to the analytical substrate; mechanisms through which the different chemical reaction conditions control the CHG process; and mechanism of action of chemical additives and foreign species. Enhanced comprehension of these different mechanisms and their mutual influence can be achieved in light of the present state of knowledge. This provides the tools to explain the reactivity of a CHG system and contributes to the clarification of several controversial aspects and the elimination of erroneous concepts in CHG.
Workplace	Institute of Analytical Chemistry
Contact	Iveta Drobníková, drobnikova@iach.cz, Tel.: 532 290 234
Year of Publishing	2012

Number of the records: 1