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HCB(11)(CF(3))(n)F(11-n)(-): Inert Anions with High Anodic Oxidation Potentials
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SYSNO ASEP 0361445 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title HCB(11)(CF(3))(n)F(11-n)(-): Inert Anions with High Anodic Oxidation Potentials Author(s) Fete, M. G. (US)
Havlas, Zdeněk (UOCHB-X) RID, ORCID
Michl, Josef (UOCHB-X) RID, ORCIDNumber of authors 3 Source Title Journal of the American Chemical Society. - : American Chemical Society - ISSN 0002-7863
Roč. 133, č. 11 (2011), s. 4123-4131Number of pages 9 s. Language eng - English Country US - United States Keywords icosahedral anions ; fluorinated carbaborane anions ; redox potentials ; gas-phase elektron detachment energy Subject RIV CC - Organic Chemistry R&D Projects IAA400550708 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) CEZ AV0Z40550506 - UOCHB-X (2005-2011) UT WOS 000288889900072 DOI 10.1021/ja111035k Annotation A new type of low nucleofile anions of general formula HCB11(CF3)nF11-n were prepared. All prepared compound were electrochemically characterized and their electrochemical potentials were compared with calculations predicting gas-phase electron detachment energy of these anions. Workplace Institute of Organic Chemistry and Biochemistry Contact asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Viktorie Chládková, Tel.: 232 002 434 Year of Publishing 2012
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