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The oxidative polymerization of p-phenylenediamine with silver nitrate: toward highly conducting micro/nanostructured silver/conjugated polymer composites
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SYSNO ASEP 0361176 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title The oxidative polymerization of p-phenylenediamine with silver nitrate: toward highly conducting micro/nanostructured silver/conjugated polymer composites Author(s) Ciric-Marjanovic, G. (RS)
Marjanovic, B. (RS)
Bober, Patrycja (UMCH-V) RID, ORCID, SAI
Rozlívková, Zuzana (UMCH-V) RID, ORCID
Stejskal, Jaroslav (UMCH-V) RID, ORCID, SAI
Trchová, Miroslava (UMCH-V) RID, ORCID
Prokeš, J. (CZ)Source Title Journal of Polymer Science. Part A - Polymer Chemistry. - : WILEY-BLACKWELL - ISSN 0887-624X
Roč. 49, č. 15 (2011), s. 3387-3403Number of pages 17 s. Language eng - English Country US - United States Keywords composites ; conjugated polymers ; poly(p-phenylenediamine) Subject RIV CD - Macromolecular Chemistry R&D Projects IAA400500905 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) IAA100500902 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) CEZ AV0Z40500505 - UMCH-V (2005-2011) UT WOS 000293279500016 DOI 10.1002/pola.24775 Annotation The oxidative polymerization of p-phenylenediamine with silver nitrate by using various oxidant/monomer mole ratios in aqueous solutions of both acetic and nitric acid was studied experimentally and computationally. The produced micro/nanostructured conducting poly(p-phenylenediamine)–silver composites, reaching the conductivities >104 S/cm, were characterized by conductivity and density measurements, gel permeation chromatography, transmission electron microscopy, UV–visible, FTIR, and Raman spectroscopies. The highest conductivity was 31,700 S/cm for poly(p-phenylenediamine) base–silver (81.4 wt % Ag). Workplace Institute of Macromolecular Chemistry Contact Eva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358 Year of Publishing 2012
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