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Comparison of Excess Volumes for Two Ternary Systems Containing (Toluene + Isooctane) with Ethanol or 1 -Butanol.

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    SYSNO ASEP0360779
    Document TypeC - Proceedings Paper (int. conf.)
    R&D Document TypeConference Paper
    TitleComparison of Excess Volumes for Two Ternary Systems Containing (Toluene + Isooctane) with Ethanol or 1 -Butanol.
    Author(s) Morávková, Lenka (UCHP-M) RID, SAI
    Wagner, Zdeněk (UCHP-M) RID, SAI, ORCID
    Sedláková, Zuzana (UCHP-M) RID, ORCID, SAI
    Aim, Karel (UCHP-M) RID, SAI
    Source TitleBook of Abstracts. - Saint Petersburg : Saint Petersburg State University, 2011 / Gotlib I. ; Victorov A. ; Smirnova N. - ISBN 5-85263-061-6
    Pagess. 389-390
    Number of pages2 s.
    Publication formCD-ROM - CD-ROM
    ActionEuropean Symposium on Applied Thermodynamics /25./
    Event date24.06.2011-27.06.2011
    VEvent locationSaint Petersburg
    CountryRU - Russian Federation
    Event typeEUR
    Languageeng - English
    CountryRU - Russian Federation
    Keywordsprimary density data ; experimental investigation ; excess volumes
    Subject RIVCF - Physical ; Theoretical Chemistry
    R&D ProjectsGP203/09/P141 GA ČR - Czech Science Foundation (CSF)
    IAA400720710 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR)
    KAN400720701 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR)
    CEZAV0Z40720504 - UCHP-M (2005-2011)
    AnnotationFrom the primary density data the corresponding values of excess volumes were calculated and fitted to a modified Redlich-Kister equation. Comparison of excess volumes for the two investigated ternary systems at temperature 298.15 K is depicted in Figure 1. It is clearly observed that binary systems (ethanol + isooctane) and (toluene + isooctane) show positive deviations from ideality, whereas binary systems (toluene + 1-butanol), (isooctane + 1-butanol) and (ethanol + toluene) possess S-shaped character. There is a pronounced temperature dependence of excess volumes in the studied systems, which will be discussed in detail.
    WorkplaceInstitute of Chemical Process Fundamentals
    ContactEva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227
    Year of Publishing2012
Number of the records: 1  

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