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Comparison of Excess Volumes for Two Ternary Systems Containing (Toluene + Isooctane) with Ethanol or 1 -Butanol.
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SYSNO ASEP 0360779 Document Type C - Proceedings Paper (int. conf.) R&D Document Type Conference Paper Title Comparison of Excess Volumes for Two Ternary Systems Containing (Toluene + Isooctane) with Ethanol or 1 -Butanol. Author(s) Morávková, Lenka (UCHP-M) RID, SAI
Wagner, Zdeněk (UCHP-M) RID, SAI, ORCID
Sedláková, Zuzana (UCHP-M) RID, ORCID, SAI
Aim, Karel (UCHP-M) RID, SAISource Title Book of Abstracts. - Saint Petersburg : Saint Petersburg State University, 2011 / Gotlib I. ; Victorov A. ; Smirnova N. - ISBN 5-85263-061-6 Pages s. 389-390 Number of pages 2 s. Publication form CD-ROM - CD-ROM Action European Symposium on Applied Thermodynamics /25./ Event date 24.06.2011-27.06.2011 VEvent location Saint Petersburg Country RU - Russian Federation Event type EUR Language eng - English Country RU - Russian Federation Keywords primary density data ; experimental investigation ; excess volumes Subject RIV CF - Physical ; Theoretical Chemistry R&D Projects GP203/09/P141 GA ČR - Czech Science Foundation (CSF) IAA400720710 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) KAN400720701 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) CEZ AV0Z40720504 - UCHP-M (2005-2011) Annotation From the primary density data the corresponding values of excess volumes were calculated and fitted to a modified Redlich-Kister equation. Comparison of excess volumes for the two investigated ternary systems at temperature 298.15 K is depicted in Figure 1. It is clearly observed that binary systems (ethanol + isooctane) and (toluene + isooctane) show positive deviations from ideality, whereas binary systems (toluene + 1-butanol), (isooctane + 1-butanol) and (ethanol + toluene) possess S-shaped character. There is a pronounced temperature dependence of excess volumes in the studied systems, which will be discussed in detail. Workplace Institute of Chemical Process Fundamentals Contact Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Year of Publishing 2012
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