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Pd2+ and Cu2+ catalyzed oxidative cross-coupling of mercaptoacetylenes and arylboronic acids
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SYSNO ASEP 0360102 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Pd2+ and Cu2+ catalyzed oxidative cross-coupling of mercaptoacetylenes and arylboronic acids Author(s) Henke, Adam (UOCHB-X)
Šrogl, Jiří (UOCHB-X)Number of authors 2 Source Title Chemical Communications. - : Royal Society of Chemistry - ISSN 1359-7345
Roč. 47, č. 14 (2011), s. 4282-4284Number of pages 3 s. Language eng - English Country GB - United Kingdom Keywords mercaptoacetylenes ; oxidative cross-coupling ; Cu/Pd catalysis Subject RIV CC - Organic Chemistry R&D Projects GA203/08/1318 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z40550506 - UOCHB-X (2005-2011) UT WOS 000288610500071 DOI 10.1039/c1cc10505a Annotation An oxidative thiolate scavenging concept in a metal catalyzed reaction is presented and demonstrated on the aerobic Pd and Cu catalyzed cross-coupling of mercaptoacetylenes with arylboronic acids. Synthetic value of the chemistry as the complementary tool to the Sonogashira protocol has been demonstrated on a series of functionalized mercaptoacetylene substrates. Workplace Institute of Organic Chemistry and Biochemistry Contact asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Viktorie Chládková, Tel.: 232 002 434 Year of Publishing 2012
Number of the records: 1