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Novel polycarbonate-based polyurethane elastomers: composition–property relationship
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SYSNO ASEP 0359231 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Novel polycarbonate-based polyurethane elastomers: composition–property relationship Author(s) Špírková, Milena (UMCH-V) RID, ORCID
Pavličevic, J. (RS)
Strachota, Adam (UMCH-V) RID, ORCID
Poreba, Rafal (UMCH-V) RID, ORCID
Bera, O. (RS)
Kaprálková, Ludmila (UMCH-V)
Baldrian, Josef (UMCH-V)
Šlouf, Miroslav (UMCH-V) RID, ORCID
Lazić, N. (RS)
Budinski-Simendic, J. (RS)Source Title European Polymer Journal. - : Elsevier - ISSN 0014-3057
Roč. 47, č. 5 (2011), s. 959-972Number of pages 14 s. Language eng - English Country GB - United Kingdom Keywords polyurethane elastomer ; polycarbonate diol ; montmorillonite Subject RIV CD - Macromolecular Chemistry R&D Projects GAP108/10/0195 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z40500505 - UMCH-V (2005-2011) UT WOS 000290701000013 DOI 10.1016/j.eurpolymj.2011.01.001 Annotation Novel all-aliphatic polycarbonate-based polyurethane (PC-PU) elastomers, as well as PC-PU nanocomposites filled with organic-modified clays were synthesized, characterized and studied. It was found that they have very attractive mechanical properties (e.g., elongation at break between 600% and 800%). The prepared PC-PUs possess a distinctly segmented structure, which is the key prerequisite for their behavior as strong physical rubbery networks. All synthesized materials melt at elevated temperatures (between 110 and 200 °C) and hence can be processed like normal thermoplastics. Besides excellent mechanical properties, the prepared elastomers and their nanocomposites showed an interesting phase behavior (which was studied by combining DMTA and modulated DSC). Workplace Institute of Macromolecular Chemistry Contact Eva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358 Year of Publishing 2012
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