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Poly[methyl(phenyl)silanediyl] modified with dansyl fluorophore: synthesis and photophysics

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    SYSNO ASEP0358851
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitlePoly[methyl(phenyl)silanediyl] modified with dansyl fluorophore: synthesis and photophysics
    Author(s) Cimrová, Věra (UMCH-V) RID, ORCID
    Výprachtický, Drahomír (UMCH-V) RID, ORCID
    Hörhold, H. H. (DE)
    Source TitleJournal of Polymer Science. Part A - Polymer Chemistry. - : WILEY-BLACKWELL - ISSN 0887-624X
    Roč. 49, č. 10 (2011), s. 2233-2244
    Number of pages12 s.
    Languageeng - English
    CountryUS - United States
    Keywordsconjugated polymers ; dansyl fluorophore ; polysilanes
    Subject RIVJA - Electronics ; Optoelectronics, Electrical Engineering
    R&D Projects1M06031 GA MŠMT - Ministry of Education, Youth and Sports (MEYS)
    IAA4050409 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR)
    CEZAV0Z40500505 - UMCH-V (2005-2011)
    UT WOS000289443900014
    DOI10.1002/pola.24654
    AnnotationThe syntheses and photophysical properties of novel luminescent polysilanes modified with dansyl fluorophores on various spacer (PMPSi-n-DNS) are reported. Influence of the alkyl chain length (n) on the photophysical properties was investigated using absorption, steady-state, and time-resolved photoluminescence (PL) spectroscopy. The excitation energy transfer from the polysilane backbone to dansyl fluorophore was proved. Polymer light-emitting devices (LEDs) were prepared from the blends of modified polysilane with electroluminescent polymer poly[2,5-dimethoxy-1,4-phenylene-1,2-ethenylene-2-methoxy-5-(2-ethylhexyloxy)-(1,4-phenylene-1,2-ethenylene)] (M3EH-PPV). Compared with LED made of neat electroluminescent polymer, a significant performance improvement of blend LEDs was demonstrated.
    WorkplaceInstitute of Macromolecular Chemistry
    ContactEva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358
    Year of Publishing2012
Number of the records: 1  

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