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Strange Redox Behavior of 1,1-Diamino-2,2-dinitroethene
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SYSNO ASEP 0357060 Document Type C - Proceedings Paper (int. conf.) R&D Document Type Conference Paper Title Strange Redox Behavior of 1,1-Diamino-2,2-dinitroethene Author(s) Šimková, Ludmila (UFCH-W) RID, ORCID
Ludvík, Jiří (UFCH-W) RID, ORCID
Klíma, Jiří (UFCH-W) RIDSource Title Sborník přednášek. XXX: Moderní elektrochemické metody. - Ústí nad Labem : BEST servis, 2010 / Navrátil Tomáš ; Barek J. - ISBN 978-80-254-6710-7 Pages s. 168-171 Number of pages 4 s. Action Moderní elektrochemické metody /30./ Event date 24.05.2009-29.05.2009 VEvent location Jetřichovice Country CZ - Czech Republic Event type WRD Language eng - English Country CZ - Czech Republic Keywords 1,1-diamino-2,2-dinitroethene ; FOX-7 ; reduction Subject RIV CG - Electrochemistry R&D Projects ME09002 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) CEZ AV0Z40400503 - UFCH-W (2005-2011) UT WOS 000283050900038 Annotation The expected product of polarographic reduction of 1,1-diamino-2,2-dinitroethene (FOX-7) in aqueous buffered solutions is ethan-1,2-diamine. But exhaustive electrolysis did not show this product. The main products are gases. Due to combination of electrochemistry and GC and with MS analysis were found following gaseous products: N-2, NO, N2O, H2O. However, no carbon containing gaseous product was found. A part of products remains probably in the water solution as inorganic ions. The degradation process accompanying the exhaustive electrolysis seems to be analogous to the reactions during explosion, but under very low concentration, cooled and slowed down by the solvent. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2011
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