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New building block for organometallic-inorganic hybrid polymers: the mixed group 15/16 element ligand complex [Cp*.sub.2./sub.Mo.sub.2./sub.(μ,η.sup.2:2./sup.-PSe).sub.2./sub.(μ-Se)](Cp* = C.sub.5./sub.Me.sub.5./sub.)
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SYSNO ASEP 0356248 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title New building block for organometallic-inorganic hybrid polymers: the mixed group 15/16 element ligand complex [Cp*2Mo2(μ,η2:2-PSe)2(μ-Se)](Cp* = C5Me5) Author(s) Bodensteiner, M. (DE)
Dušek, Michal (FZU-D) RID, ORCID, SAI
Kubicki, M. M. (FR)
Pronold, M. (DE)
Scheer, M. (DE)
Wachter, J. (DE)
Zabel, M. (DE)Number of authors 7 Source Title European Journal of Inorganic Chemistry. - : Wiley - ISSN 1434-1948
Roč. 2010, č. 33 (2010), s. 5298-5303Number of pages 6 s. Language eng - English Country DE - Germany Keywords phosphorus ; selenium ; copper ; coordination modes ; polymers Subject RIV BM - Solid Matter Physics ; Magnetism CEZ AV0Z10100521 - FZU-D (2005-2011) UT WOS 000285229800013 DOI 10.1002/ejic.201000796 Annotation The synthesis and spectroscopic characterization of [Cp*2Mo2P2Se3] (Cp* = C5Me5) and its use as a molecular building block in the formation of copper(I) halide polymers is described. The following new compounds were described: [(Cp*2Mo2P2Se3)2(CuBr)2], [(Cp*2Mo2P2Se3)(CuI)3(CH3CN)]n (two isomeric forms one of them being incommensurate) and [(Cp*2Mo2P2Se3)(P4Se3)(CuI)2]n. Workplace Institute of Physics Contact Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579 Year of Publishing 2011
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