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The first metallacarborane triple-decker complexes with a bridging pentaphospholyl ligand

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    SYSNO ASEP0356240
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleThe first metallacarborane triple-decker complexes with a bridging pentaphospholyl ligand
    Author(s) Loginov, D.A. (RU)
    Vinogradov, M.M. (RU)
    Starikova, ZA. (RU)
    Petrovskii, PV. (RU)
    Holub, Josef (UACH-T) SAI, RID, ORCID
    Kudinov, AR. (RU)
    Source TitleCollection of Czechoslovak Chemical Communications. - : Ústav organické chemie a biochemie AV ČR, v. v. i. - ISSN 0010-0765
    Roč. 75, č. 9 (2010), s. 981-993
    Number of pages13 s.
    Languageeng - English
    CountryCZ - Czech Republic
    Keywordsboranes ; metallacarboranes ; iron ; sandwich compounds
    Subject RIVCA - Inorganic Chemistry
    R&D ProjectsLC523 GA MŠMT - Ministry of Education, Youth and Sports (MEYS)
    CEZAV0Z40320502 - UACH-T (2005-2011)
    UT WOS000282524200007
    DOI10.1135/cccc2010052
    AnnotationVisible light irradiation of cations [(Carb)Fe(eta-C6H6)](+) in the presence of Cp*Fe(eta-cyclo-P-5) affords the mu-pentaphospholyl triple-decker complexes [(Carb)Fe(mu-eta:eta-cyclo-P-5)FeCp*](+) (Carb = 9-SMe2-7,8-C2B9H10 (3a) and 1-t-BuNH-1,7,9-C3B8H10 (3b)). Structures of 3a- and 3b[Co(eta-7,8-C2B9H11)(2)] were determined by X-ray diffraction. Bonding in 3a, 3b and mononuclear building blocks was analyzed by energy decomposition analysis.
    WorkplaceInstitute of Inorganic Chemistry
    ContactJana Kroneislová, krone@iic.cas.cz, Tel.: 311 236 931
    Year of Publishing2011
Number of the records: 1  

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