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The effect of the pH on the oxidative polymerization of aniline and the morphology and properties of the products
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SYSNO ASEP 0355746 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title The effect of the pH on the oxidative polymerization of aniline and the morphology and properties of the products Author(s) Sapurina, I. Yu. (RU)
Stejskal, Jaroslav (UMCH-V) RID, ORCID, SAISource Title Russian Chemical Reviews. - : TURPION LTD - ISSN 0036-021X
Roč. 79, č. 12 (2010), s. 1123-1143Number of pages 21 s. Language eng - English Country RU - Russian Federation Keywords polyaniline ; conducting polymer ; nanotubes Subject RIV CD - Macromolecular Chemistry R&D Projects ME 847 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) CEZ AV0Z40500505 - UMCH-V (2005-2011) UT WOS 000286598400004 DOI 10.1070/RC2010v079n12ABEH004140 Annotation The synthesis and properties of the most popular and widely used electrically conducting polymer, polyaniline, are considered. The proposed mechanisms of the molecular synthesis and self-assembly of macromolecules occurring during the polymerization agree with the large body of experimental data. The acidity of the reaction medium is demonstrated to affect the mechanism on aniline oxidative polymerization and the formation of various types of supramolecular structures, namely nanoglobules, nanofibres, nanotubes and microspheres. Workplace Institute of Macromolecular Chemistry Contact Eva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358 Year of Publishing 2011
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