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Synthesis of Perfluoroalkylated Carboranes by Cross-Metathesis of Allylcarboranes and Perfluoroalkylpropenes
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SYSNO ASEP 0355604 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Synthesis of Perfluoroalkylated Carboranes by Cross-Metathesis of Allylcarboranes and Perfluoroalkylpropenes Author(s) Eignerová, Barbara (UOCHB-X)
Janoušek, Zbyněk (UACH-T)
Dračínský, Martin (UOCHB-X) RID, ORCID
Kotora, M. (CZ)Number of authors 4 Source Title Synlett. - : Georg Thieme Verlag - ISSN 0936-5214
-, č. 6 (2010), s. 885-888Number of pages 4 s. Language eng - English Country DE - Germany Keywords metathesis ; perfluoroalkylation ; ruthenium ; carboranes ; metallacarboranes Subject RIV CC - Organic Chemistry R&D Projects LC06077 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) LC523 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) CEZ AV0Z40550506 - UOCHB-X (2005-2011) AV0Z40320502 - UACH-T (2005-2011) UT WOS 000275848800008 DOI 10.1055/s-0029-1219546 Annotation A ruthenium complex (Hoveyda–Grubbs second-generation) catalyzed cross-metathesis of allylcarboranes with perfluoroalkylpropenes under standard reaction conditions furnished perfluoroalkylated carboranes in good isolated yields (31–53%). The reaction proceeded with various carboranes and carborane sandwich complexes bearing the bridging allylthioether moiety. This method constitutes a simple and versatile procedure for the preparation of fluorophilic carboranes. Workplace Institute of Organic Chemistry and Biochemistry Contact asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Viktorie Chládková, Tel.: 232 002 434 Year of Publishing 2011
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