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High-Band-Gap Polycrystalline Monolayers of a 12-Vertex p-Carborane on Au(111)

SYSNO ASEP	0352048
Document Type	J - Journal Article
R&D Document Type	Journal Article
Subsidiary J	Článek ve WOS
Title	High-Band-Gap Polycrystalline Monolayers of a 12-Vertex p-Carborane on Au(111)
Author(s)	Wrochem von, F. (DE) Scholz, F. (DE) Gao, D. (DE) Nothofer, H. G. (DE) Yasuda, A. (DE) Wessels, J. M. (DE) Roy, S. (US) Chen, X. (US) Michl, Josef (UOCHB-X)_{RID, ORCID}
Number of authors	9
Source Title	Journal of Physical Chemistry Letters. - : American Chemical Society - ISSN 1948-7185 Roč. 1, č. 24 (2010), s. 3471-3477
Number of pages	7 s.
Language	eng - English
Country	US - United States
Keywords	molecular structure ; quantum chemistry ; general theory
Subject RIV	CF - Physical ; Theoretical Chemistry
CEZ	AV0Z40550506 - UOCHB-X (2005-2011)
UT WOS	000285446800009
DOI	10.1021/jz101215h
Annotation	We have observed that p-carboranes tethered to gold by thiolate linkers form polycrystalline monolayers which are incommensurate with the Au(111) substrate. The incommensurability results from the strong interactions between adjacent p-carborane cages (1.6 eV/molecule) and from the adlayer lattice spacing, which is defined by the cage diameter.
Workplace	Institute of Organic Chemistry and Biochemistry
Contact	asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Viktorie Chládková, Tel.: 232 002 434
Year of Publishing	2011

Number of the records: 1