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Electrorheology of suspensions of variously protonated polyaniline particles under steady and oscillatory shear

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    SYSNO ASEP0349956
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve SCOPUS
    TitleElectrorheology of suspensions of variously protonated polyaniline particles under steady and oscillatory shear
    Author(s) Stěnička, M. (CZ)
    Pavlínek, V. (CZ)
    Sáha, P. (CZ)
    Blinova, Natalia V. (UMCH-V)
    Stejskal, Jaroslav (UMCH-V) RID, ORCID, SAI
    Quadrat, Otakar (UMCH-V)
    Source TitleApplied Rheology. - : KERSCHENSTEINER VERLAG GMBH - ISSN 1430-6395
    Roč. 20, č. 5 (2010), 55371_1-55371_7
    Number of pages7 s.
    Languageeng - English
    CountryDE - Germany
    Keywordspolyaniline ; electrorheology ; steady shear
    Subject RIVBK - Fluid Dynamics
    R&D ProjectsGA202/09/1626 GA ČR - Czech Science Foundation (CSF)
    CEZAV0Z40500505 - UMCH-V (2005-2011)
    EID SCOPUS77957676088
    DOI10.3933/ApplRheol-20-55371
    AnnotationElectrorheological (ER) and dielectric properties of silicone-oil suspensions of polyaniline (PANI) particles protonated with phosphoric and tetrafluoroboric acids to various doping level have been investigated. The particle conductivity was thus varied between the order of 10-9 S/cm and 10-4 S/cm. The dynamic yield stresses obtained at controlled shear rate mode viscometry, the storage moduli from the oscillatory shear experiments and the dielectric relaxation times from frequency dependences of dielectric constant and loss factor were used as criteria of rigidity or elasticity of ER structures and particle mobility in the electric field. The conductivity of suspension particles plays a decisive role in their ER behaviour. The ER efficiency increased as conductivity of dispersed particles raised, irrespective of the type of employed acid used for the protonation of PANI.
    WorkplaceInstitute of Macromolecular Chemistry
    ContactEva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358
    Year of Publishing2011
Number of the records: 1  

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