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A combined experimental and theoretical study on the complexation of the ammonium cation with valinomycin
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SYSNO ASEP 0349803 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title A combined experimental and theoretical study on the complexation of the ammonium cation with valinomycin Author(s) Makrlík, E. (CZ)
Dybal, Jiří (UMCH-V) RID, ORCID
Vaňura, P. (CZ)Source Title Monatshefte fur Chemie. - : Springer - ISSN 0026-9247
Roč. 141, č. 11 (2010), s. 1191-1194Number of pages 4 s. Language eng - English Country AT - Austria Keywords antibiotics ; macrocycles ; stability constant Subject RIV CD - Macromolecular Chemistry R&D Projects 1ET400500402 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) CEZ AV0Z40500505 - UMCH-V (2005-2011) UT WOS 000283608400003 DOI 10.1007/s00706-010-0395-0 Annotation From extraction experiments in the two-phase water/nitrobenzene system and gamma-activity measurements, the stability constant of the valinomycin-ammonium complex in nitrobenzene saturated with water was determined. Further, the structure of the resulting complex was derived by means of density functional theory (DFT) calculations. Workplace Institute of Macromolecular Chemistry Contact Eva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358 Year of Publishing 2011
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