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Zeolites Efficiently Promote the Cyclization of Nonactivated Unsaturated Alcohols
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SYSNO ASEP 0349031 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Zeolites Efficiently Promote the Cyclization of Nonactivated Unsaturated Alcohols Author(s) Pérez-Mayoral, E. (ES)
Matos, I. (PT)
Fonseca, I. (PT)
Čejka, Jiří (UFCH-W) RID, ORCID, SAISource Title Chemistry - A European Journal. - : Wiley - ISSN 0947-6539
Roč. 16, č. 40 (2010), s. 12079-12082Number of pages 4 s. Language eng - English Country DE - Germany Keywords alcohols ; cyclization ; ethers Subject RIV CF - Physical ; Theoretical Chemistry R&D Projects FT-TA5/005 GA MPO - Ministry of Industry and Trade (MPO) CEZ AV0Z40400503 - UFCH-W (2005-2011) UT WOS 000284060200005 DOI 10.1002/chem.201001593 Annotation Excellent cyclization: Zeolites H-BEA, H-MFI, H-FAU, and H-STF were found to be efficient, selective, and reusable catalysts in the cyclization of cis-4-decenol, affording the corresponding tetrahydrofuran with excellent yields to provide a new synthetic route to alkylfurans. Brønsted and Lewis acid sites in the zeolites under study are probably the active sites, because both of them catalyze this reaction. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2011
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