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Zeolites Efficiently Promote the Cyclization of Nonactivated Unsaturated Alcohols

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    SYSNO ASEP0349031
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleZeolites Efficiently Promote the Cyclization of Nonactivated Unsaturated Alcohols
    Author(s) Pérez-Mayoral, E. (ES)
    Matos, I. (PT)
    Fonseca, I. (PT)
    Čejka, Jiří (UFCH-W) RID, ORCID, SAI
    Source TitleChemistry - A European Journal. - : Wiley - ISSN 0947-6539
    Roč. 16, č. 40 (2010), s. 12079-12082
    Number of pages4 s.
    Languageeng - English
    CountryDE - Germany
    Keywordsalcohols ; cyclization ; ethers
    Subject RIVCF - Physical ; Theoretical Chemistry
    R&D ProjectsFT-TA5/005 GA MPO - Ministry of Industry and Trade (MPO)
    CEZAV0Z40400503 - UFCH-W (2005-2011)
    UT WOS000284060200005
    DOI10.1002/chem.201001593
    AnnotationExcellent cyclization: Zeolites H-BEA, H-MFI, H-FAU, and H-STF were found to be efficient, selective, and reusable catalysts in the cyclization of cis-4-decenol, affording the corresponding tetrahydrofuran with excellent yields to provide a new synthetic route to alkylfurans. Brønsted and Lewis acid sites in the zeolites under study are probably the active sites, because both of them catalyze this reaction.
    WorkplaceJ. Heyrovsky Institute of Physical Chemistry
    ContactMichaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196
    Year of Publishing2011
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