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Novel soluble fluorene-thienothiadiazole and fluorene-carbazole copolymers for optoelectronics
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SYSNO ASEP 0348860 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Novel soluble fluorene-thienothiadiazole and fluorene-carbazole copolymers for optoelectronics Author(s) Cimrová, Věra (UMCH-V) RID, ORCID
Kmínek, Ivan (UMCH-V)
Výprachtický, Drahomír (UMCH-V) RID, ORCIDSource Title Macromolecular Symposia. - : Wiley - ISSN 1022-1360
Roč. 295, č. 1 (2010), s. 65-70Number of pages 6 s. Action Prague Meetings on Macromolecules /73./ New Frontiers in Macromolecular Science: From Macromolecular Concepts of Living Matter to Polymers for Better Quality of Life Event date 05.07.2009-09.07.2009 VEvent location Prague Country CZ - Czech Republic Event type WRD Language eng - English Country DE - Germany Keywords fluorene – thienothiadiazole copolymers ; photovoltaics ; fluorene-carbazole copolymers Subject RIV JA - Electronics ; Optoelectronics, Electrical Engineering R&D Projects 1M06031 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) IAA4050409 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) CEZ AV0Z40500505 - UMCH-V (2005-2011) UT WOS 000288038700007 DOI 10.1002/masy.200900060 Annotation Optical, photophysical, electrochemical and photoelectrical properties of novel soluble low-bandgap fluorene – thienothiadiazole based copolymers and luminescent fluorene – carbazole copolymers, were studied. Fluorene – thienothiadiazole copolymers possess low bandgap, high electron affinity and exhibit reversible electrochromic behaviour. Spectroelectrochemical study was performed and optical switching demonstrated. Photovoltaic devices made of blends of copolymers and fullerene derivative [60]PCBM with the power conversion efficiency 2–3% were prepared. On the other hand, the fluorene-carbazole copolymers exhibit blue photoluminescence with high quantum efficiency in solution and also in thin films. Light-emitting devices with intensive broad bluish-green-white emission were fabricated. Workplace Institute of Macromolecular Chemistry Contact Eva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358 Year of Publishing 2011
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