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Electron transfer across the polarized interface between water and a hydrophobic redox-active ionic liquid

SYSNO ASEP	0348376
Document Type	J - Journal Article
R&D Document Type	Journal Article
Subsidiary J	Článek ve WOS
Title	Electron transfer across the polarized interface between water and a hydrophobic redox-active ionic liquid
Author(s)	Langmaier, Jan (UFCH-W)_{RID, ORCID, SAI} Trojánek, Antonín (UFCH-W)_RID Samec, Zdeněk (UFCH-W)_{RID, ORCID}
Source Title	Electrochemistry Communications. - : Elsevier - ISSN 1388-2481 Roč. 12, č. 10 (2010), s. 1333-1335
Number of pages	3 s.
Language	eng - English
Country	NL - Netherlands
Keywords	redox-active ionic liquid ; membrane ; cyclic voltammetry
Subject RIV	CG - Electrochemistry
R&D Projects	ME08098 GA MŠMT - Ministry of Education, Youth and Sports (MEYS)
	GAP206/10/1231 GA ČR - Czech Science Foundation (CSF)
CEZ	AV0Z40400503 - UFCH-W (2005-2011)
UT WOS	000284444500019
DOI	10.1016/j.elecom.2010.07.013
Annotation	Here we report the synthesis of a new redox-active ionic liquid (IL), (ferrocenylmethyl)dodecyldimethylammonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate that can be used to form the polarizable water│IL interface at an elevated temperature (43 °C). Experimental approach is based on the cyclic voltammetry of the charge transfer processes occurring at the IL membrane supported on a thin microporous filter. Evidence is provided of the interfacial electron transfer between the ferrocenated cation of IL and an electron acceptor, IrCl62−, in the adjacent aqueous phase.
Workplace	J. Heyrovsky Institute of Physical Chemistry
Contact	Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196
Year of Publishing	2011

Number of the records: 1