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Mathematical Modelling of Supercritical CO2 Extraction of Volatile Oils from Aromatic Plants
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SYSNO ASEP 0346702 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Mathematical Modelling of Supercritical CO2 Extraction of Volatile Oils from Aromatic Plants Author(s) Grosso, C. (PT)
Coelho, J.P. (PT)
Pessoa, F.L.P. (BR)
Fareleira, J.M.N.A. (PT)
Barroso, J.G. (PT)
Urieta, J.S. (ES)
Palavra, A.F. (PT)
Sovová, Helena (UCHP-M) RID, ORCID, SAISource Title Chemical Engineering Science. - : Elsevier - ISSN 0009-2509
Roč. 65, č. 11 (2010), s. 3579-3590Number of pages 12 s. Language eng - English Country GB - United Kingdom Keywords supercritical fluid extraction ; modelling ; volatile oils Subject RIV CI - Industrial Chemistry, Chemical Engineering CEZ AV0Z40720504 - UCHP-M (2005-2011) UT WOS 000278602000021 DOI 10.1016/j.ces.2010.02.046 Annotation The modelling of the experimental data of the extraction of the volatile oil from six aromatic plants (coriander, fennel, savoury, winter savoury, cotton lavender and thyme) was performed using five mathematical models, based on differential mass balances. In all cases the extraction was internal diffusion controlled and the internal mass transfer coefficient (ks) has been found to change with pressure, temperature and particle size. For fennel, savoury and cotton lavender, the external mass transfer and the equilibrium phase also influenced the second extraction period, since ks changed with the tested flow rates. In general, the axial dispersion coefficient could be neglected for the conditions studied, since Peclet numbers were high. On the other hand, the solute-matrix interaction had to be considered in order to ensure a satisfactory description of the experimental data. Workplace Institute of Chemical Process Fundamentals Contact Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Year of Publishing 2011
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