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Observation of an anomalous cage effect in multiphoton photodissociation of acetylene clusters
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SYSNO ASEP 0346597 Document Type C - Proceedings Paper (int. conf.) R&D Document Type Conference Paper Title Observation of an anomalous cage effect in multiphoton photodissociation of acetylene clusters Author(s) Votava, Ondřej (UFCH-W) RID, ORCID
Fárník, Michal (UFCH-W) RID, ORCID
Poterya, Viktoriya (UFCH-W) RID, ORCID
Ončák, Milan (UFCH-W) ORCID, RID
Slavíček, Petr (UFCH-W) RID
Buck, U. (DE)Source Title XVII Symposium on Atomic, Cluster and Surface Physics 2010. - Innsbruck : Innsbruck University Press, 2010 - ISBN 978-3-902719-52-2 Pages s. 270-272 Number of pages 3 s. Action XVII Symposium on Atomic, Cluster and Surface Physics 2010 Event date 24.01.2010-29.01.2010 VEvent location Obergurgl Country AT - Austria Event type WRD Language eng - English Country AT - Austria Keywords acetylene clusters ; photochemistry ; photodissociation Subject RIV CF - Physical ; Theoretical Chemistry R&D Projects KAN400400651 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) KJB400400902 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) GA203/09/0422 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z40400503 - UFCH-W (2005-2011) Annotation The profound effect of the solvent on the photochemistry has been known for a long time. In 1936, Franck and Rabinowitch introduced the concept of the cage effect to explain the lowering of the iodine photodissociation yield upon solvation. More generally, the slowing down the molecular fragments and preventing the molecules from the dissociation by the solvent cage are manifestations of solvent induced photostability. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2011
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