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Speciation of Fe in Fe-modified zeolite catalysts
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SYSNO ASEP 0346577 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Speciation of Fe in Fe-modified zeolite catalysts Author(s) Smoláková, L. (CZ)
Grygar, Tomáš (UACH-T)
Čapek, L. (CZ)
Schneeweiss, Oldřich (UFM-A) RID, ORCID
Zbořil, R. (CZ)Source Title Journal of Electroanalytical Chemistry. - : Elsevier - ISSN 1572-6657
Roč. 647, č. 1 (2010), s. 8-19Number of pages 12 s. Language eng - English Country CH - Switzerland Keywords solid state speciation ; Fe2O3 ; heterogeneous catalysts Subject RIV CB - Analytical Chemistry, Separation CEZ AV0Z40320502 - UACH-T (2005-2011) AV0Z20410507 - UFM-A (2005-2011) UT WOS 000280863200002 DOI 10.1016/j.jelechem.2010.05.017 Annotation Fe-modified zeolites were prepared by four impregnation methods, characterized by diffuse reflectance UV-Vis spectroscopy and voltammetry of microparticles, and tested in oxidative dehydrogenation of ethane (ODH). Less common species identified in the catalysts were Fe(III) oxide nanoclusters inside the zeolite pores and amorphous Fe2O3. Monomeric and dimeric Fe(III) ions were most selective in ODH, Fe(III) oxide nanoclusters overoxidized ethane. Workplace Institute of Inorganic Chemistry Contact Jana Kroneislová, krone@iic.cas.cz, Tel.: 311 236 931 Year of Publishing 2011
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