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Activity and stability of polyaniline-sulfate-based solid acid catalysts for the transesterification of triglycerides and esterification of fatty acids with methanol
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SYSNO ASEP 0346405 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Activity and stability of polyaniline-sulfate-based solid acid catalysts for the transesterification of triglycerides and esterification of fatty acids with methanol Author(s) Zieba, A. (PL)
Drelinkiewicz, A. (PL)
Konyushenko, Elena (UMCH-V) RID, ORCID
Stejskal, Jaroslav (UMCH-V) RID, ORCID, SAISource Title Applied Catalysis A - General. - : ELSEVIER SCIENCE BV - ISSN 0926-860X
Roč. 383, 1/2 (2010), s. 169-181Number of pages 13 s. Language eng - English Country NL - Netherlands Keywords biodiesel ; transesterification ; triacetin Subject RIV CD - Macromolecular Chemistry R&D Projects IAA400500905 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) CEZ AV0Z40500505 - UMCH-V (2005-2011) UT WOS 000280624900022 DOI 10.1016/j.apcata.2010.05.042 Annotation A polymeric catalyst, polyaniline-sulfate, was studied in the transesterification of triglycerides (triacetin, castor oil) and esterification of fatty acid. ricinoleic acid with methanol at mild conditions (temperature of 50-60 degrees C). Polymer powder (PANI-S) and three samples of various contents of polymer deposited on carbon support were examined. The samples of catalysts, before and after catalytic tests were characterized by BET, FT-IR, XRD and SEM techniques. The acid capacity was also determined. All the samples were found to be active solid acid catalysts in both tested reactions. Workplace Institute of Macromolecular Chemistry Contact Eva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358 Year of Publishing 2011
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