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Straightforward Synthesis of Substituted p-Quinones: Isolation of a Key Intermediate and Use as a Bridging Ligand in a Diruthenium Complex

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    SYSNO ASEP0345814
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleStraightforward Synthesis of Substituted p-Quinones: Isolation of a Key Intermediate and Use as a Bridging Ligand in a Diruthenium Complex
    Author(s) Das, H. S. (DE)
    Weisser, F. (DE)
    Schweinfurth, D. (DE)
    Su, Ch. Y. (CN)
    Bogani, C. (DE)
    Fiedler, Jan (UFCH-W) RID, ORCID
    Sarkar, B. (DE)
    Source TitleChemistry - A European Journal. - : Wiley - ISSN 0947-6539
    Roč. 16, č. 10 (2010), s. 2977-2981
    Number of pages5 s.
    Languageeng - English
    CountryDE - Germany
    Keywordscyclic voltammetry ; quinones ; ruthenium
    Subject RIVCF - Physical ; Theoretical Chemistry
    R&D ProjectsOC 140 GA MŠMT - Ministry of Education, Youth and Sports (MEYS)
    OC09043 GA MŠMT - Ministry of Education, Youth and Sports (MEYS)
    CEZAV0Z40400503 - UFCH-W (2005-2011)
    UT WOS000275943400002
    DOI10.1002/chem.200903409
    AnnotationA new transamination method is reported for the synthesis of diamino-substituted p-quinones (see scheme). Asymmetrically substituted p-quinones are shown to be key intermediates in this reaction. The redox properties of these ligands are discussed and their utility in coordination and redox chemistry is shown with a representative example.
    WorkplaceJ. Heyrovsky Institute of Physical Chemistry
    ContactMichaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196
    Year of Publishing2011
Number of the records: 1  

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