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Oxidation of Dichloromethane over Pt and Au Impregnated on Extracted and Calcined TiO2-ZrO2 Supports
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SYSNO ASEP 0345363 Document Type C - Proceedings Paper (int. conf.) R&D Document Type Conference Paper Title Oxidation of Dichloromethane over Pt and Au Impregnated on Extracted and Calcined TiO2-ZrO2 Supports Author(s) Matějová, Lenka (UCHP-M) RID, ORCID, SAI
Pitkäaho, S. (FI)
Ojala, S. (FI)
Cajthaml, Tomáš (MBU-M) RID, ORCID
Keiski, R.L. (FI)
Šolcová, Olga (UCHP-M) RID, ORCID, SAISource Title Proceedings. - Oulu : University of Oulu, 2010 / Pongrácz E. ; Hyvärinen M. - ISBN 978-951-42-6199-2 Pages s. 66-69 Number of pages 4 s. Action Clean Air Research at the University of Oulu Event date 03.06.2010 VEvent location Oulu Country FI - Finland Event type EUR Language eng - English Country FI - Finland Keywords CVOC oxidation ; oxidic catalysts ; extraction Subject RIV CF - Physical ; Theoretical Chemistry R&D Projects GP104/09/P290 GA ČR - Czech Science Foundation (CSF) GA104/09/0694 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z40720504 - UCHP-M (2005-2011) AV0Z50200510 - MBU-M (2005-2011) Annotation In this study the definite correlation between textural and structural properties and catalytic performances of platinum- and gold-impregnated TiO2-ZrO2 catalysts in DCM total oxidation has been found. Textural properties, micro/mesoporosity, dispersion of noble metal particles, structural properties and morphology of four laboratory and one commercial catalysts were characterized by nitrogen physisorption at 77, chemisorption, XRD, SEM, TPR and TPD techniques. Besides the initial light-off tests carried out over all the catalysts at high WHSV of 150 dm3gcat-1h-1 also the effect of various WHSV on the catalytic activity and selectivity of platinum and gold-impregnated and calcined TiO2-ZrO2 catalysts was investigated. The durability of all tested catalysts was also studied. Workplace Institute of Chemical Process Fundamentals Contact Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Year of Publishing 2011
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