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Self-assembled polyaniline nanotubes and nanoribbons/titanium dioxide nanocomposites
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SYSNO ASEP 0345183 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Self-assembled polyaniline nanotubes and nanoribbons/titanium dioxide nanocomposites Author(s) Radoičic, M. (CS)
Šaponjic, Z. (CS)
Nedeljkovic, J. (CS)
Ciric-Marjanovic, G. (RS)
Stejskal, Jaroslav (UMCH-V) RID, ORCID, SAISource Title Synthetic Metals. - : Elsevier - ISSN 0379-6779
Roč. 160, 11-12 (2010), s. 1325-1334Number of pages 10 s. Language eng - English Country CH - Switzerland Keywords nanocomposites ; nanoribbons ; nanostructures Subject RIV JI - Composite Materials R&D Projects GA202/09/1626 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z40500505 - UMCH-V (2005-2011) UT WOS 000279625900034 DOI 10.1016/j.synthmet.2010.04.010 Annotation Self-assembled polyaniline (PANI) nanotubes, accompanied with nanoribbons, were synthesized by the oxidative polymerization of aniline with ammonium peroxydisulfate in an aqueous medium, in the presence of colloidal titanium dioxide (TiO2) nanoparticles of 4.5 nm size, without added acid. The morphology, structure, and physicochemical properties of the PANI/TiO2 nanocomposites, prepared at various initial aniline/TiO2 mole ratios, were studied by scanning (SEM) and transmission (TEM) electron microscopies, FTIR, Raman and inductively coupled plasma optical emission (ICP-OES) spectroscopies, elemental analysis, X-ray powder diffraction (XRPD), conductivity measurements, and thermogravimetric analysis (TGA). The electrical conductivity of PANI/TiO2 nanocomposites increases in the range 3.8 × 10−4 to 1.1 × 10−3 S cm−1 by increasing aniline/TiO2 mole ratio from 1 to 10. Workplace Institute of Macromolecular Chemistry Contact Eva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358 Year of Publishing 2011
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