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On the Mechanism of Electrochemical Reduction of Dodecylpyridinium Bromide in Aprotic Media. An Impedance Study
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SYSNO ASEP 0343503 Document Type C - Proceedings Paper (int. conf.) R&D Document Type Conference Paper Title On the Mechanism of Electrochemical Reduction of Dodecylpyridinium Bromide in Aprotic Media. An Impedance Study Author(s) Hromadová, Magdaléna (UFCH-W) RID, ORCID, SAI
Kolivoška, Viliam (UFCH-W) RID, ORCID
Pospíšil, Lubomír (UFCH-W) RID, ORCIDSource Title Sborník přednášek. XXX. Moderní elektroanalytické metody. - Ústí nad Labem : BEST servis, 2010 / Navrátil Tomáš ; Barek J. - ISBN 978-80-254-6710-7 Pages s. 77-79 Number of pages 3 s. Action Modern Electroanalytical Methods /30./ Event date 24.05.2010-28.05.2010 VEvent location Jetřichovice Country CZ - Czech Republic Event type EUR Language eng - English Country CZ - Czech Republic Keywords dodecylpyridinium bromide ; reduction mechanism ; impendance spectroscopy Subject RIV CG - Electrochemistry R&D Projects GA203/08/1157 GA ČR - Czech Science Foundation (CSF) GA203/09/0705 GA ČR - Czech Science Foundation (CSF) IAA400400802 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) CEZ AV0Z40400503 - UFCH-W (2005-2011) UT WOS 000283050900017 Annotation Reduction mechanism of n-dodecylpyridinium bromide (DPBr) in dimethylsulfoxide has been studied. Based on the classical polarographis methods as well as on the use of AC voltammetry and impendance spectroscopy techniques it was shown that DPBr is reduced in a reversible one electron transfer step followed by the dimerization of the corresponding radical species. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2011
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