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Non-destructive Depth Profiling of the Activated Ti-Zr-V Getter by Means of Excitation Energy Resolved Photoelectron Spectroscopy

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    SYSNO ASEP0343393
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleNon-destructive Depth Profiling of the Activated Ti-Zr-V Getter by Means of Excitation Energy Resolved Photoelectron Spectroscopy
    Author(s) Pavluch, J. (CZ)
    Zommer, L. (PL)
    Mašek, K. (CZ)
    Skála, T. (IT)
    Šutara, F. (CZ)
    Nehasil, V. (CZ)
    Píš, I. (CZ)
    Polyak, Yaroslav (UFCH-W)
    Source TitleAnalytical Sciences - ISSN 0910-6340
    Roč. 26, č. 2 (2010), s. 209-215
    Number of pages7 s.
    Languageeng - English
    CountryJP - Japan
    Keywordsnon-evaporable getter materials ; XPS methods
    Subject RIVCF - Physical ; Theoretical Chemistry
    CEZAV0Z40400503 - UFCH-W (2005-2011)
    UT WOS000274977700012
    EID SCOPUS77949895185
    DOI10.2116/analsci.26.209
    AnnotationNon-evaporable Ti-Zr-V ternary getters (NEGs) were studied by means of excitation energy resolved photoelectron spectroscopy (ERXPS). We attempted a quantitative study of the in-depth redistribution of the NEG components during activation. The samples were prepared ex-situ by DC magnetron sputtering on a stainless-steel substrate. The ERXPS measurements were carried out at two incident photoelectron beam angles at energies of 110, 195, 251, 312, 397 and 641 eV. Besides these photon energies, also standard X-ray photoelectron spectroscopy (XPS) was used at a photon energy of 1254 eV. We accumulated Ti 3s, Ti 3p, Ti 3d, V 3s, V 3p, V 3d, Zr 3p, Zr 3d, Zr 4s, Zr 4p, Zr 4d, C 1s, O 1s and O 2s photoelectron peak intensities as functions of the kinetic energies given to them. Under simplifying assumptions, Monte-Carlo calculations of the activated sample concentration profiles were performed to fit the measured spectra intensities.
    WorkplaceJ. Heyrovsky Institute of Physical Chemistry
    ContactMichaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196
    Year of Publishing2011
Number of the records: 1  

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