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Oxygen and proton reduction by decamethylferrocene in non-aqueous acidic media
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SYSNO ASEP 0342760 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Oxygen and proton reduction by decamethylferrocene in non-aqueous acidic media Author(s) Su, B. (CH)
Hatay, I. (CH)
Ge, P. Y. (CH)
Méndez, M. A. (CH)
Corminboeuf, C. (CH)
Samec, Zdeněk (UFCH-W) RID, ORCID
Ersöz, M. (TR)
Girault, H. H. (CH)Source Title Chemical Communications. - : Royal Society of Chemistry - ISSN 1359-7345
Roč. 46, č. 17 (2010), s. 2918-2919Number of pages 2 s. Language eng - English Country GB - United Kingdom Keywords ferrocene derivatives ; liquid interface ; perchloric acid Subject RIV CG - Electrochemistry R&D Projects GA203/07/1257 GA ČR - Czech Science Foundation (CSF) OC 177 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) CEZ AV0Z40400503 - UFCH-W (2005-2011) UT WOS 000276632800007 DOI 10.1039/b926963k Annotation Experimental studies and density functional theory (DFT) computations suggest that oxygen and proton reduction by decamethylferrocene (DMFc) in 1,2-dichloroethane involves protonated DMFc, DMFcH(+), as an active intermediate species, producing hydrogen peroxide and hydrogen in aerobic and anaerobic conditions, respectively. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2011
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