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ACE applied to the quantitative characterization of benzo-18-crown-6-ether binding with alkali metal ions in a methanol-water solvent system
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SYSNO ASEP 0342722 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title ACE applied to the quantitative characterization of benzo-18-crown-6-ether binding with alkali metal ions in a methanol-water solvent system Author(s) Ehala, Sille (UOCHB-X) RID, ORCID
Makrlík, E. (CZ)
Toman, Petr (UMCH-V) RID, ORCID
Kašička, Václav (UOCHB-X) RID, ORCIDNumber of authors 4 Source Title Electrophoresis. - : Wiley - ISSN 0173-0835
Roč. 31, č. 4 (2010), s. 702-708Number of pages 7 s. Language eng - English Country DE - Germany Keywords affinity capillary electrophoresis ; alkali metal ions ; binding constant Subject RIV CB - Analytical Chemistry, Separation R&D Projects GA203/08/1428 GA ČR - Czech Science Foundation (CSF) GA203/09/0675 GA ČR - Czech Science Foundation (CSF) 1ET400500402 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) CEZ AV0Z40550506 - UOCHB-X (2005-2011) AV0Z40500505 - UMCH-V (2005-2011) UT WOS 000275239500017 DOI 10.1002/elps.200900581 Annotation Affinity capillary electrophoresis was applied to quantitative evaluation of non-covalent binding interactions between benzo-18-crown-6-ether (B18C6) and several alkali metal ions, Li+, Na+, K+, Rb+ and Cs+, in a mixed binary solvent system, methanol–water (50/50, v/v). The apparent binding (stability) constants of B18C6-alkali metal ion complexes in the above hydro-organic medium were determined. KW: affinity capillary electrophoresis; alkali metal ions; binding constant. Workplace Institute of Organic Chemistry and Biochemistry Contact asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Viktorie Chládková, Tel.: 232 002 434 Year of Publishing 2011
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