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Formation of a 1-Zircona-2,5-disilacyclopent-3-yne: Coordination of 1,4-Disilabutatriene to Zirconocene?
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SYSNO ASEP 0342617 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Formation of a 1-Zircona-2,5-disilacyclopent-3-yne: Coordination of 1,4-Disilabutatriene to Zirconocene? Author(s) Lamač, Martin (UFCH-W) RID, ORCID, SAI
Spannenberg, A. (DE)
Jiao, H. (DE)
Hansen, S. (DE)
Baumann, W. (DE)
Arndt, P. (DE)
Rosenthal, U. (DE)Source Title Angewandte Chemie - International Edition. - : Wiley - ISSN 1433-7851
Roč. 49, č. 16 (2010), s. 2937-2940Number of pages 4 s. Language eng - English Country DE - Germany Keywords 1-Zircona-2,5-disilacyclopent-3-yne ; 1,4-Disilabutatriene ; zirconocene Subject RIV CF - Physical ; Theoretical Chemistry CEZ AV0Z40400503 - UFCH-W (2005-2011) UT WOS 000277131200023 DOI 10.1002/anie.201000021 Annotation Alkyne under stress: A novel metallacycle containing one Zr atom, two Si atoms, and a C=C bond has been prepared and its structure elucidated (Zr green, Si blue, C gray). According to X-ray data, spectral properties, and DFT calculations, the bonding situation in this compound is characterized as a 1-metalla-2,5-disilacyclopent-3-yne with a weak metal-triple-bond interaction. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2011
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